To perform the operation from your root account:
% cd /System/Library/CoreServicesThink of applying back all permissions: -rw-r--r-- on root:wheel.
% mv DefaultDesktop.jpg DefaultDesktop.jpg.org
% cp /Library/Desktop\ Pictures/Aqua\ Blue.jpg /System/Library/CoreServices/DefaultDesktop.jpg
% chown root:wheel /System/Library/CoreServices/DefaultDesktop.jpg
% chmod 644 /System/Library/CoreServices/DefaultDesktop.jpg
PS: do not perform the procedure if you do not feel confident with the terminal
